常用金属表面缓蚀自组装膜及其研究方法  

INHIBITIVE SELF-ASSEMBLED MONOLAYERS ON SURFACES OF COMMONLY-USED METALS AND RELATED RESEARCH METHODS

作　　者：王海人[1] 江燕[1] 屈钧娥[1] 李文维[1] 陈凤[1] 张强[2] 

机构地区：[1]湖北大学材料科学与工程学院,武汉430062 [2]中国石油西南油气田分公司天然气研究院,成都610213

出　　处：《中国腐蚀与防护学报》2012年第4期273-284,共12页Journal of Chinese Society For Corrosion and Protection

基　　金：国家自然科学基金(51001045);湖北省自然科学基金(2009CDB347)资助

摘　　要：简要介绍了常用活性金属表而主要涉及的缓蚀自组装膜体系以及缓蚀膜自组装行为的主要影响因素,并重点综述了电化学疗法、谱学技术、显微镜技术以及接触角测试等研究方法在活性金属表面缓蚀自组装膜研究领域的应用。Constructing inhibitive self-assembled monolayers on metal surfaces is a new kind of anticorro- sion method developed in recent years. The research objects have been changed gradually from inert metals （such as gold and platinum） to commonly-used active metals and their alloys. In this paper, the mainly in- volved assembling systems for common active metals and the major influencing factors on the self-assembling behavior of inhibitor molecules are introduced, and the characterization methods for investigation of inhibitive self-assembled monolayers, including electrochemical means, spectroscopes, microscopes and contact angle mea- surement etc, are reviewed.

关 键 词：活性金属 缓蚀自组装膜 自组装体系 影响因素 研究方法 

分 类 号：O647.3[理学—物理化学] TG174.4[理学—化学]