Synthesis and Crystal Structure Analysis of 2-Amino-4,6-bis(diphenoxyl phosphoramide)-1,3,5-triazine  

作　　者：张楠 成昌梅 王如骥 

机构地区：[1]Key Laboratory of Bioorganic Phosphorus Chemistry&Chemical Biology(Ministry of Education),Department of Chemistry,Tsinghua University [2]Tsinghua University

出　　处：《Chinese Journal of Structural Chemistry》2012年第7期1042-1046,共5页结构化学（英文）

摘　　要：A disubstituted triazine compound, namely, 2-amino-4,6-bis（diphenoxyl phosphorramide）-1,3,5-triazine, which is an inherent flame retardant monomer, was synthesized specifically, and its structure was characterized by using NMR spectrum and X-ray single-crystal diffraction. Unit cell parameters： space group P21/c, Z=4, a=8.7494（15）, b=27.518（5）, c=12.511（2）,β=109.323（16） , Z=4, V=2842.7（9）β3 , Dc=1.380 g/cm3 , F（000）=1224 and Mr=590.46. All the atoms are in the general positions.A disubstituted triazine compound, namely, 2-amino-4,6-bis（diphenoxyl phosphorramide）-1,3,5-triazine, which is an inherent flame retardant monomer, was synthesized specifically, and its structure was characterized by using NMR spectrum and X-ray single-crystal diffraction. Unit cell parameters： space group P21/c, Z=4, a=8.7494（15）, b=27.518（5）, c=12.511（2）,β=109.323（16） , Z=4, V=2842.7（9）β3 , Dc=1.380 g/cm3 , F（000）=1224 and Mr=590.46. All the atoms are in the general positions.

关 键 词：2-amino-4 6-bis（diphenoxyl phosphoramide）-1 3 5-triazine inherentflame retardant X-ray single-crystal diffraction crystal structure 

分 类 号：O626[理学—有机化学]