八面体Fe_3O_4纳米颗粒的制备及微波吸收性能  被引量:4

Synthesis and microwave absorption properties of octahedral Fe_3O_4 nanoparticles

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作  者:倪经[1] 魏恭 吕涛 邵晓萍[3] 谭士杰[1] 代波[3] 

机构地区:[1]西南应用磁学研究所,四川绵阳621010 [2]空军住绵阳地区军事代表室,四川绵阳621000 [3]西南科技大学材料科学与工程学院,四川绵阳621000

出  处:《磁性材料及器件》2012年第4期21-24,30,共5页Journal of Magnetic Materials and Devices

基  金:装备预先研究项目(51323040311);四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地开放基金资助项目(10zxkf28)

摘  要:利用简便的氧化沉淀法制备出了结晶度高、粒径均一的八面体Fe3O4纳米颗粒。通过X射线衍射(XRD)、透射电子显微镜(TEM)和振动样品磁强计(VSM)对产物的结构、形貌、粒径及磁性能进行了表征。制备的八面体Fe3O4纳米颗粒平均粒径为43nm,在室温下表现出铁磁性,比饱和磁化强度和矫顽力分别为74.2 A.m2/kg和7.4 kA/m。利用矢量网络分析仪对Fe3O4纳米颗粒-石蜡复合样品在0.5~18GHz频率范围内的电磁参数进行了测量,研究了复合样品的微波吸收性能。结果表明,复合样品具有良好的微波吸收,吸收峰位随着样品厚度的增加向低频移动,峰值和吸收峰数目也随样品厚度而变化,当匹配厚度为2.8 mm时,在10.8 GHz反射损失最小值达到了-22.5 dB。Octahedral Fe3O4 nanoparticles with high crystallinity and uniform size were synthesized by simple oxidation precipitation method. The phase structures, morphology, particle size and magnetic property of the products were characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM) and vibrating sample magnetometer (VSM), respectively'. The products with an average size of 43nm exhibits room-temperature ferromagnetic behavior, and specific saturation magnetization of 74.2 A-m2/kg and coercive of 7.4 kA/m. The electromagnetic parameters of composites of octahedral Fe3O4 nanoparticles and paraffin wax were measured using vector network analyzer in the frequency range of 0.5 to 18 GHz, and the microwave absorbing properties of composites were investigated. It was found that the composites have excellent microwave absorption properties. The reflection loss (RL) peak shifts to a lower frequency with increasing thickness, the peak 'value and number also change with the thickness. For sample with matching thickness of 2.8 mm, the minimal reflection loss reaches --22.5 dB at 10.8 GHz

关 键 词:FE3O4纳米粒子 磁性能 微波吸收性能 

分 类 号:TB383[一般工业技术—材料科学与工程] TM277[电气工程—电工理论与新技术]

 

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