钛酸盐(钴、镓)沸石分子筛的合成与表征  

Synthesis and Characterization of Metal Titanate Zeolites

作　　者：霍丽华[1] 王旭[1] 赵经贵[1] 马淑杰[2] 

机构地区：[1]黑龙江大学化学化工学院,哈尔滨150080 [2]吉林大学化学系

出　　处：《应用化学》2000年第3期322-324,共3页Chinese Journal of Applied Chemistry

基　　金：黑龙江省自然科学基金! (9732 )

摘　　要：Cobalt titanate and gallium titanate zeolites were synthesized hydrothermally using tetraethylammonium hydroxide and/or tetrapropylammonium bromide as template. The study of the effects of pH value, amount and feed order of template and reaction time on the products indicated that the most important factor was the pH value of the reaction medium, which must be in between 2 to 6 to give zeolite crystals. The products have been characterized by XRD, SEM, DTA, IR, UV Vis and N 2 adsorption techniques to be microporous zeolites, where Ti atoms are in complexation forms of TiO 4 and TiO 6. The Co titanate and Ga titanate zeolites had specific area of 263 and 204 m 2/g, respectively.Cobalt titanate and gallium titanate zeolites were synthesized hydrothermally using tetraethylammonium hydroxide and/or tetrapropylammonium bromide as template. The study of the effects of pH value, amount and feed order of template and reaction time on the products indicated that the most important factor was the pH value of the reaction medium, which must be in between 2 to 6 to give zeolite crystals. The products have been characterized by XRD, SEM, DTA, IR, UV Vis and N 2 adsorption techniques to be microporous zeolites, where Ti atoms are in complexation forms of TiO 4 and TiO 6. The Co titanate and Ga titanate zeolites had specific area of 263 and 204 m 2/g, respectively.

关 键 词：钛酸钴 钛酸镓 水热合成 沸石分子筛 催化性能 

分 类 号：TQ426.6[化学工程] O643.36[理学—物理化学]