电化学聚合漆酚-铕配合物的合成及性质  

Synthesis and Property of Polymeric Complex of Electropolyurushiol(EPU) with Europium

作　　者：唐洁渊[1] 高锋[1] 章文贡[1] 王文[1] 

机构地区：[1]福建师范大学高分子研究所,福州350007

出　　处：《应用化学》2000年第3期325-327,共3页Chinese Journal of Applied Chemistry

基　　金：福建省自然科学基金

摘　　要：Title polymeric complex(EPU Eu(Ⅲ)) was obtained from triisobutoxy euro pium Eu(C 3H 7O) 3 with electropolyurushiol in isobutyl alcohol. The structure and property of the complex were characterized by FT IR, XPS, DMTA, AES, TG DTA and fluorescence spectrophotometry. The complex with Eu(Ⅲ) content reached up to 9 6% was insoluble in most organic solvents. Its electric resistance was 1 25×10 5 MΩ(that of EPU was 7 90×10 4 MΩ). Its T g and thermal resistance was considerably greater than that of EPU.Title polymeric complex(EPU Eu(Ⅲ)) was obtained from triisobutoxy euro pium Eu(C 3H 7O) 3 with electropolyurushiol in isobutyl alcohol. The structure and property of the complex were characterized by FT IR, XPS, DMTA, AES, TG DTA and fluorescence spectrophotometry. The complex with Eu(Ⅲ) content reached up to 9 6% was insoluble in most organic solvents. Its electric resistance was 1 25×10 5 MΩ(that of EPU was 7 90×10 4 MΩ). Its T g and thermal resistance was considerably greater than that of EPU.

关 键 词：电化学聚合 漆酚 铕 配合物 聚合物 性质 合成 

分 类 号：O634.3[理学—高分子化学] O631.5[理学—化学]