含二氮杂萘酮结构聚醚砜酮膜的微波等离子体处理研究  

STUDY OF MODIFICATION OF POLY(PHTHALAZINONE ETHER SULFONE KETONE) FILM TREATED BY CARBON DIOXIDE MICROWAVE PLASMA

作　　者：彭静[1] 蹇锡高[1] 李琦 邓新绿[2] 顾彪[3] 

机构地区：[1]大连理工大学高分子材料系,大连116012 [2]大连理工大学三束材料改性国家重点实验室,大连116023 [3]大连理工大学电磁工程系,大连116023

出　　处：《高分子学报》2000年第3期354-357,共4页Acta Polymerica Sinica

基　　金：国家自然科学基金项目!(基金号 5 9473 0 19);大连理工大学三束材料改性国家重点实验室资助课题

摘　　要：Low temperature plasma has been used to modify the surface properties of polymers to a large extent. The effects of ECR microwave plasma with carbon dioxide (CO\-2) on the wettability of the poly(phthalazinone ether sulfone ketone) (PPESK) surface were discussed. Results showed that a shorter treatment time and a higher discharge power could give the best wettability of PPESK films. The toughness of the treated film surface increased with the discharge power. The wettability of PPESK films treated by CO\-2 plasma declined with the aging time after treatment, and the changing rate of different power is resemble. The increase in water contact angle for plasma treated PPESK surfaces upon ageing is mainly ascribed to the surface rearrangement of macromolecular segments, the loss of oxygen\|containing moieties introduced by the plasma treatment. ESCA analysis of CO\-2 plasma treated polymer surfaces showed that carbonyl groups could be increased by carbon oxide plasma treatment in short time.Low temperature plasma has been used to modify the surface properties of polymers to a large extent. The effects of ECR microwave plasma with carbon dioxide (CO\-2) on the wettability of the poly(phthalazinone ether sulfone ketone) (PPESK) surface were discussed. Results showed that a shorter treatment time and a higher discharge power could give the best wettability of PPESK films. The toughness of the treated film surface increased with the discharge power. The wettability of PPESK films treated by CO\-2 plasma declined with the aging time after treatment, and the changing rate of different power is resemble. The increase in water contact angle for plasma treated PPESK surfaces upon ageing is mainly ascribed to the surface rearrangement of macromolecular segments, the loss of oxygen\|containing moieties introduced by the plasma treatment. ESCA analysis of CO\-2 plasma treated polymer surfaces showed that carbonyl groups could be increased by carbon oxide plasma treatment in short time.

关 键 词：CO2微波等离子体 表面性能 PPESK膜 改性 

分 类 号：O631[理学—高分子化学]