高邻位羟甲基含量的酚醛胶粘剂制备及其性能研究  

Preparation of Phenol-Formaldehyde Adhesives for High-Ortho Methylol Group Content and Its Properties

作　　者：谢建军[1] 曾念[1] 李娜[1] 肖淼[1] 饶小波[1] 吴义强[1] 

机构地区：[1]中南林业科技大学材料科学与工程学院,湖南长沙410004

出　　处：《湘潭大学自然科学学报》2012年第2期66-69,共4页Natural Science Journal of Xiangtan University

基　　金：湖南省教育厅重点项目(10A130);湖南省重大专项基金项目资助

摘　　要：通过氢氧化钡和氢氧化钠复合催化、间苯二酚改性的两步甲醛加入法工艺制备了低游离醛、高邻位羟甲基含量的酚醛胶黏剂.采用正交试验设计考察了甲醛与苯酚摩尔比、氢氧化钡用量、氢氧化钠用量和反应时间对制备的酚醛胶黏剂游离醛、游离酚和羟甲基含量的影响,确定了优选制备工艺条件:甲醛与苯酚的摩尔比为1.7∶1,氢氧化钡质量浓度为3.0%、氢氧化钠质量浓度为2.0%、反应时间为2.0h,得到的酚醛胶黏剂游离醛、游离酚含量分别为0.298%、4.192%,羟甲基含量为36.29%.Somephenol-formaldehyde adhesives with the contents of low free formaldehyde and high-ortho methylol group are synthesized with barium hydroxide and sodium hydroxide as the composite catalyst and by adding separately formaldehyde in two times. The effects of the molar ratios of phenol and formaldehyde, the mass concentrations of barium hydroxide and sodium hydroxide, and the reaction time on the con- tents of free formaldehyde, free phenol and methylol group in the obtained phenol-formaldehyde adhesives are investigated by means of orthogonal experiment. The results have shown that the optimum conditions of the preparing phenol-formaldehyde adhesives are as follow, the molar ratio of phenol and formaldehyde is 1.7, the mass concentration of barium hydroxide is 3.0 %, the mass concentration of sodium hydroxide is 2.0% and the reaction time is 2 h. For the adhesive of the above-mentioned formula, the contents of free formaldehyde and phenol are 0. 298% and 4. 192% respectively, and the content of the methylol group is 36.29%.

关 键 词：酚醛树脂 胶粘剂 复合催化剂 间苯二酚改性 正交实验 

分 类 号：TU630[建筑科学—建筑技术科学]