聚羟基丁酸酯的等温与非等温结晶动力学  

Isothermal and Non-Isothermal Crystallization Kinetics of Poly(3-Hydroxybutyrate)

作　　者：李海东[1] 管明章[1] 程凤梅[1] 李婷婷[1] 

机构地区：[1]长春工业大学化学工程学院,吉林长春130012

出　　处：《高分子材料科学与工程》2012年第8期60-63,共4页Polymer Materials Science & Engineering

基　　金：国家自然科学基金资助项目(50621302)

摘　　要：用差示扫描量热法(DSC)研究了聚羟基丁酸酯(PHB)的等温与非等温结晶动力学。采用Avrami方程分析了等温结晶动力学,Avrami指数n≈2,表明PHB以异相成核的二维平面晶体方式生长,等温结晶活化能为82.4 kJ/min。采用Jeziorny法和莫志深法分析了PHB的非等温结晶动力学,Avrami指数n≈3,表明PHB非等温结晶过程以异相成核的三维球晶方式生长。The crystallization kinetics during the isothermal crystalization and nonisothermal crystallization of poly （3-hydroxybutyrate） （PHB） were investigated by means of differential scanning calorimetry（DSC）. The Avrami analysis was performed to obtain the kinetics parameters. The value of Avrami index n, is about D, indicating a twodimensional （2D） growth and heterogeneous nucleation in the process of isothermal crystallization. The activation energy for isothermal crystallization is 82.4 kJ/min, respectively. In the process of nonisothermal crystallization of PHB, the value of Avrami index n, is about 3, which demonstrates a three-dimensional spherulitic growth on heterogeneous nucleation.

关 键 词：聚羟基丁酸酯 等温结晶 非等温结晶 结晶动力学 

分 类 号：TQ314.1[化学工程—高聚物工业]