Facile Synthesis of Dendritic Hydroxyl-terminated Cyanuric Chloride Derivatives and Their Properties  

作　　者：林休休 周建华 徐冬梅 

机构地区：[1]College of Chemistry,Chemical Engineering and Materials Science,National Engineering Laboratory for Modern Silk,Key Laboratory of Organic Synthesis of Jiangsu Province,Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application,Soochow University,Suzhou,Jiangsu 215123,China [2](Suzhou)Zhongke Nanotech Coating Co.LTD,Suzhou,Jiangsu 215024,China

出　　处：《Chinese Journal of Chemistry》2012年第7期1485-1489,共5页中国化学（英文版）

基　　金：Supporting information for this article is availaigle on the WWW under http：//dx.doi.org/10.1002/cjoc.201100557 or from the author.Acknowledgement The authors are greateful for the financial supports from the National Natural Science Foundation of China （No. 21074085）, the open research foundation of the National Engineering Laboratory for Modem Silk, Soochow University （No. SS115801） and the open research foundation of the Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University （No. KJS0911）.

摘　　要：Novel dendritic compounds G1.5（OH）4 and G1.5（OH）8 with peripheral hydroxyl were synthesized under mild conditions from eyanuric chloride, ethylene diamine, ethanolamine and diethanolamine. The products could be separated and purified through dispersion and precipitation in organic solvents with good yields （over 93.0%） and high purity （above 98.0%, HPLC）. The structures of the products were characterized by 1R, MS, 1H NMR and elementary analysis. G1.5（OH）4 and Gl.5（OH）8 could be dissolved in polar solvents such as methanol, water and dimethylsulfoxide. TGA analysis showed that G1.5（OH）4 and G1.5（OH）8 had good thermo stability. The aqueous solutions ofG1.5（OH）4 and G1.5（OH）8 exhibited low surface tension.Novel dendritic compounds G1.5（OH）4 and G1.5（OH）8 with peripheral hydroxyl were synthesized under mild conditions from eyanuric chloride, ethylene diamine, ethanolamine and diethanolamine. The products could be separated and purified through dispersion and precipitation in organic solvents with good yields （over 93.0%） and high purity （above 98.0%, HPLC）. The structures of the products were characterized by 1R, MS, 1H NMR and elementary analysis. G1.5（OH）4 and Gl.5（OH）8 could be dissolved in polar solvents such as methanol, water and dimethylsulfoxide. TGA analysis showed that G1.5（OH）4 and G1.5（OH）8 had good thermo stability. The aqueous solutions ofG1.5（OH）4 and G1.5（OH）8 exhibited low surface tension.

关 键 词：DENDRITIC cyanuric chloride ethylene diamine HYDROXYL surface activity 

分 类 号：TQ223.1[化学工程—有机化工] Q421[生物学—神经生物学]