无机盐离子对变黏酸流变性影响的研究  

Influence of Inorganic Ions on Rheological Property of Viscosity-variable Acid

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作  者:王彦玲[1] 徐超[1] 王增宝[1] 赵晓龙[2] 金家锋[1] 

机构地区:[1]中国石油大学(华东)石油工程学院,青岛266555 [2]中原油田井下特种作业处,濮阳457164

出  处:《精细石油化工进展》2012年第7期1-4,共4页Advances in Fine Petrochemicals

基  金:山东省科技攻关计划项目(No.2010GSF10601)

摘  要:采用自制的新型黏弹性表面活性剂(VES-TCJ),配制出性能稳定的变黏酸。通过模拟变黏酸与碳酸盐岩反应形成的成胶酸,考察了不同无机盐离子对变黏酸的流变性的影响。试验结果表明,Ca2+和Mg2+均能使变黏酸获得较大的表观黏度,在储层酸化过程中起到转向分流作用;在高矿化度地层中变黏酸仍具有较大的表观黏度;少量的Fe3+对变黏酸的变黏特性影响较小,但Fe3+浓度较高时变黏酸的黏度急剧下降,将失去转向分流能力。Viscosity -variable acids with stable performance were prepared in laboratory using self- made new viscoelastic surfactant ( VES - TCJ). The effects of different inorganic ions on the rheological properties of the viscosity - variable acids were investigated by simulating acid - rock reaction to form gelling acid. The experimental results showed that both Ca2~ and Mg2~ greatly increased the apparent viscosity of the acid system, thus viscosity -variable acids could play the role of diversion in reservoir acidization. The apparent viscosity of the viscosity - variable acid was still high in reservoir with high salinity. The effect of a small quantity of Fe3~ on the viscosity of the acid system was little, but the apparent viscosity of the viscosity - variable acid could rapidly decrease and viscosity -variable acid could lose the diversion function when the Fe3~ concentration was enough high.

关 键 词:酸化 变黏酸 无机盐离子 流变性 表观黏度 

分 类 号:TE39[石油与天然气工程—油气田开发工程]

 

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