磁性纳米粒子负载钯催化有机合成反应研究进展  

Progress in Organic Synthesis Reactions Catalyzed by Palladium Supported on Magnetic Nanoparticles

作　　者：袁定重[1] 黄斌[1] 

机构地区：[1]东华理工大学材料科学与工程系,南昌330013

出　　处：《有机化学》2012年第8期1368-1379,共12页Chinese Journal of Organic Chemistry

基　　金：江西省自然科学基金(No.20114BAB213011);东华理工大学博士科研启动基金(No.DHBK1010)资助项目~~

摘　　要：磁性纳米粒子负载钯催化的有机合成反应,由于具有催化活性高,催化剂在外加磁场作用下即可快速分离和重复使用等特点,已引起了人们的广泛关注.综述了近年来磁性纳米粒子负载钯催化有机合成反应的研究进展,载体包括Fe3O4纳米粒子、有机小分子修饰的磁性纳米粒子、SiO2包覆的磁性纳米粒子、碳修饰磁性纳米粒子、羟基磷灰石包覆的磁性纳米粒子和有机高分子修饰的磁性纳米粒子等.The organic synthesis reactions catalyzed by palladium supported on magnetic nanoparticles have attracted consideralbe attention because catalytic activity is excellent and supported catalyst can be separated easily with an external magnet and reused several times.In this paper,the advances in the organic synthesis reactions catalyzed by palladium supported on magnetic nanoparticles have been reviewed.Fe3O4nanoparticles,organic small molecles modified Fe3O4nanoparticles,SiO2 modified Fe3O4nanoparticles,carbon modified magnetic nanopartilces,hydroxyapatite modified magnetic nanopartilces and polymer modified magnetic nanopartilces were used to support the palladium catalysts.

关 键 词：有机合成反应 磁性纳米粒子 负载钯催化剂 催化 

分 类 号：O621.25[理学—有机化学] O643.3[理学—化学]