南海北部边缘盆地氮气气源追踪与判识  

Nitrogen Gas Source Tracking and Distinguishing in Margin Basins, Northern South China Sea

作　　者：何家雄[1] 颜文[1] 崔洁[2] 马文宏 祝有海[4] 龚晓峰[1] 张景茹[1] 

机构地区：[1]中国科学院边缘海地质重点实验室 [2]广东省技术经济研究发展中心 [3]中海石油有限公司湛江分公司勘探开发部 [4]中国地质科学院矿产资源研究所

出　　处：《海相油气地质》2012年第3期67-71,共5页Marine Origin Petroleum Geology

基　　金：国家自然科学基金项目(编号:41176052);国家重点基础研究发展计划项目(编号:2009CB219501)联合资助

摘　　要：南海北部边缘盆地油气勘探中陆续发现较丰富的二氧化碳(CO2)和氮气(N2)等非烃气气藏,同时亦发现了一些含N2、富N2的天然气层。这些CO2和N2非烃气主要富集于西北部边缘莺歌海盆地中央泥底辟带新近系及第四系浅层中。根据N2地质地球化学特征,可将本区N2划分为大气成因、壳源型有机成因和壳源型有机-无机混合成因三种主要成因类型。结合温压双控热模拟岩石产氮气实验结果,以及N2等非烃气在平面上分区分块、剖面上分带分层的局部性富集特点,追踪判识并确定N2气源主要由来自不同成熟演化阶段的中新统及上新统海相泥岩气源岩的N2与多种物理化学和岩石脱气作用所形成的无机N2相互混合而构成。Abundant CO2 and N2 gas reservoirs and other N2-bearing gas reservoirs are discovered in the Neogene and Quarternary shallow beds of Central Mud diapir Zone in Yinggehai Basin,South China Sea during recent 20 years′oil and gas exploration.According to geological and geochemical characteristics of N2,the N2 gas in this area can be divided into three types in genesis,i.e.the atmosphere genesis,the crust organic genesis and the crust-derived organic-inorganic-mixed genesis.Combined with results from the nitrogen-producing experiments under T-and P-controlled thermal simulation and the characteristics of partial enrichment in plane and layering and zoning enrichment in vertical,it is determined the N2 gas is tracked to the mixture of the N2 that mainly yielded from Pliocene and Miocene marine gas source mudstone during different stages of maturation with the N2 that formed from physical and chemical actions and rock degassing.

关 键 词：南海北部 新近系 古近系 海相气源岩 氮气 气体成因 成因类型 

分 类 号：TE112.111[石油与天然气工程—油气勘探]