高硫煤电解催化氧化对煤质的影响  

Changes of High sulfur Coal Behavior in Coal Electrolytic Oxidation Desulfurization

作　　者：张鸿波[1,2] 李丽[1] 王志杰[2] 

机构地区：[1]黑龙江科技学院,黑龙江哈尔滨150027 [2]山西潞安环保能源开发股份有限公司,山西长治046000

出　　处：《矿产综合利用》2012年第4期51-54,共4页Multipurpose Utilization of Mineral Resources

基　　金：教育部科学技术研究重点项目资助(211049);黑龙江自然科学基金项目(E201058);黑龙江省普通高等学校青年骨干教师支持计划项目(1155G48);山西潞安集团博士后基金项目(2009026)

摘　　要：以山西石坷节煤样为原料,利用红外光谱(FT-IR)和热失重分析(TG)等主要测试技术研究了煤在酸性条件下电化学催化氧化脱硫对煤质的影响。试验结果表明,电化学催化氧化后煤中硫含量显著减少,全硫脱除率82.5%,其中无机硫脱除率高达90%,有机硫脱除率为50.5%。这表明电化学反应可以使煤样中的硫分有效脱除,此外还脱除煤中大量的矿物质,降低了灰分含量,并且使煤的燃烧性能变好,提高了精煤的发热量。论文还讨论了煤的电化学脱硫机理。The effects of electrochemical oxidation on Shikejie coal desulfurization in acid electrolytic system were studied with FT-IR,TG and other analysis and testing technology. The test results show that after electrochemical catalytic oxidation of coal the sulfur contents in coal deceased rapidly. The desulfurization ratio of total, inorganic and organic sulfurs were 82.5% ,90% and 50.5% ,respectively. The electrochemical catalytic oxidation decreased ash content in coal, increased caloricity of coal. The electrochemical desulfurization mechanism of coal was studied.

关 键 词：红外光谱 热失重分析 电化学 煤 脱硫 

分 类 号：TD94[矿业工程—选矿]