聚吡咯/石墨烯复合导电材料的制备及性能表征  

Preparation and performance characterization of polypyrrole/graphene composite electrode material

作　　者：王春晓[1] 任鹏刚[1] 刘蓬[2] 谢利[1] 张华[1] 方长青[1] 

机构地区：[1]西安理工大学印刷包装工程学院包装工程系,陕西西安710048 [2]西北工业大学理学院应用化学系,陕西西安710072

出　　处：《功能材料》2012年第16期2150-2152,2155,共4页Journal of Functional Materials

基　　金：国家自然科学基金资助项目(51073128)

摘　　要：利用电化学合成和化学还原方法制备了超级电容器用聚吡咯/石墨烯(PPy/GNs)复合电极材料,分别对比了恒电流和脉冲电流条件下石墨烯对电极材料电化学性能的影响,断口形貌及电性能测试结果表明,石墨烯因其良好的导电性能可有效提高电极的比容量,与聚吡咯(PPy)相比,恒电流制备的PPy/GNs(DC-PPy/GNs)电极比容量提高了13.5%。另外发现,脉冲电流制备的PPy/GNs(PC-PPy/GNs)超级电容器具有更大的比容量和更好的循环稳定性。导通时间为100ms时,PC-PPy/GNs复合电极材料在100mV/s的扫描速率下比容量可达280F/g。Polypyrrole（PPy） and polypyrrole/graphene（PPy/GNs） electrode composites were prepared via elec- trochemical polymerization and chemical reduction from pyrrole（Py） and GO（graphite oxide）. Fracture mor- phology and electric performance of the composites were characterized by scanning electron microscope and VMP2 electrochemical workstation. It is found that the specific capacitance of PPy/GNs composite electrode synthesized by direct current is 13.5% higher than that of polypyrrole electrode. Comparison of electrochemical performance between PPy and PPy/GNs composites indicates that the PPy/GNs composite synthesized by pulse current（PC） have higher capacitance and better rate capability than that of direct current（DC）. The specific ca- pacitance can reach to 280F/g at the 100mV/s scanning rate.

关 键 词：聚吡咯 氧化石墨 脉冲电流 超级电容器 电化学 

分 类 号：TQ311[化学工程—高聚物工业]