4,4′-bpy配位的铕羧酸配合物谱学性质和量化研究  

Study on the Spectroscopic Properties and Quantum Chemistry Calculation of Eu-carboxylate Coordination Polymer by 4,4′-bpy Coordinated

作　　者：赵玲艳[1] 任莉[1] 张浩[1] 

机构地区：[1]河北联合大学迁安学院,河北迁安063000

出　　处：《河北化工》2012年第9期39-42,共4页Hebei Chemical Industry

基　　金：河北联合大学青年基金资助项目(z201103)

摘　　要：通过水热法合成以第二配体4,4′-联吡啶作为桥联剂的稀土-间甲基苯甲酸配合物[Eu(C8H7O2)3(4,4′-bpy)0.5]n。对该配合物进行了紫外光谱的表征和量化计算,结果表明,此配合物在光学材料方面具有潜在应用价值。To synthesize the rare earth-organic carboxylate coordination polymer[Eu（C8H7O2）3（4,4′-bpy）0.5]n）with the 4,4′-bipy ligand functioned as a bridge by hydrothermally method,and have the UV-vis spectra and quantum chemistry calculation.The results showed that the polymer had the potential values as double refractive index materials.

关 键 词：铕羧酸配合物 紫外光谱 量化计算 

分 类 号：O641[理学—物理化学]