新型二茂铁酒石酰腙聚合物的合成、表征及应用  

Synthesis,Characterization and Application for New Type Ferrocenyl-hydrazone Coordination Polymer

作　　者：蒋虎南[1] 林云[1] 林展如[1] 

机构地区：[1]四川师范大学化学与材料科学学院,成都610066

出　　处：《材料导报》2012年第16期55-59,共5页Materials Reports

基　　金：国家自然科学基金(2013420-01);四川师范大学研究生科研创新项目([2011]3)

摘　　要：通过1,1′-二乙酰基二茂铁与酒石酸二甲酰肼反应合成二茂铁酒石酰腙聚合物(Fc-JS)后,再与金属(M=Cu、Co、Ni、Mn、Cd)乙酸盐配位,得到5种二茂铁酒石酰腙金属配位聚合物(Fc-JS-M)。用IR、TGA、XRD、荧光光谱及介电常数进行表征。结果表明,在适于移动通信应用的0.2～2.0GHz频段,Fc-JS-M有较高的介电常数(ε′)、较低的介电损耗(ε″),将其制成的倒F型微带天线有良好的缩波性能和较高的增益。因此Fc-JS-M作为一种天线新材料,可用于小型化、多功能化及高增益的双频微带天线。Five ferrocenyl-hydrazone tartrate through preparation of the monomers starting from 1, acetate （M= Cu, Co, Ni, Mn, Cd） coordination. Their metallic coordination polymers （Fc-JS-M） were synthesized l＇-diacetylferrocene , hydrazine tartrate and them metallic salts properties were characterized by IR. TGA. XRD. fluorescence spectrum and dielectric parameters. The results show that Fc J＆M in 0. 2- 2. 0GHz frequency section for mobile communication have high dielectric constant （ε＇） and lower dielectric loss （ε＂）, the inverted F microstrip antenna pre- pared from Fc-JS-M have good compactwave properties and directional pattern,as well as higher gain. However, as a new antenna material, it can be used to a double frequency microstrip antenna of small type, multifunction and high gain.

关 键 词：二茂铁酰腙配位聚合物 合成 表征 天线应用 

分 类 号：TB31[一般工业技术—材料科学与工程] TB39