Solution Combustion Synthesis of TiO_2 and Its Use for Fabrication of Photoelectrode for Dye-sensitized Solar Cell  

作　　者：Shyan-Lung Chung Ching-Mei Wang 

机构地区：[1]Department of Chemical Engineering,National Cheng Kung University [2]Advanced Optoelectronic Technology Center,National Cheng Kung University

出　　处：《Journal of Materials Science & Technology》2012年第8期713-722,共10页材料科学技术（英文版）

基　　金：Support of this research by the National Science Council of Taiwan under Grant No. NSC 100-2221-E-006-214;partial support under Contract No. 101-D0204-6 by the Bureau of Energy, Ministry of Economic Affairs of Taiwan;the LED Lighting Research Center, NCKU

摘　　要：Three different types of TiO2 nano powders were synthesized by a solution combustion synthesis （SCS） method using three different fuels and for comparison, another type of Ti2 nano powder was synthesized by calcination of titanyl hydroxide. These TiO2 nano powders were used to fabricate photoelectrodes for the dye-sensitized solar cell （DSSC） and their performance was compared to that of the DSSC fabricated with Degussa P25 TiO2. The results showed that the SCS TiO2 could work well as photoelectrode for DSSC. The SCS TiO2 contained impurities of C and/or S, thus exhibiting visible light absorption and reduced band gap. The open circuit voltage and the fill factor both varied little among the various TiO2 and thus both had little effect on the photoelectrical conversion efficiency （η）. However, the variation of r/was seen to be in quite a good agreement with that of the short circuit current （Isc）, suggesting that r/was dominated by Isc. lsc was found to be enhanced by light scattering effect due to the presence of large particles but reduced by high impurity content due to an increase in electron transfer resistance. In addition, the specific surface area of the powders was found to be an important factor affecting the Isc and thus the η.Three different types of TiO2 nano powders were synthesized by a solution combustion synthesis （SCS） method using three different fuels and for comparison, another type of Ti2 nano powder was synthesized by calcination of titanyl hydroxide. These TiO2 nano powders were used to fabricate photoelectrodes for the dye-sensitized solar cell （DSSC） and their performance was compared to that of the DSSC fabricated with Degussa P25 TiO2. The results showed that the SCS TiO2 could work well as photoelectrode for DSSC. The SCS TiO2 contained impurities of C and/or S, thus exhibiting visible light absorption and reduced band gap. The open circuit voltage and the fill factor both varied little among the various TiO2 and thus both had little effect on the photoelectrical conversion efficiency （η）. However, the variation of r/was seen to be in quite a good agreement with that of the short circuit current （Isc）, suggesting that r/was dominated by Isc. lsc was found to be enhanced by light scattering effect due to the presence of large particles but reduced by high impurity content due to an increase in electron transfer resistance. In addition, the specific surface area of the powders was found to be an important factor affecting the Isc and thus the η.

关 键 词：TIO2 Combustion synthesis Dye-sensitized solar cells 

分 类 号：TM914.4[电气工程—电力电子与电力传动] O643.36[理学—物理化学]