物理法制备的纳米过渡金属催化剂上CO的氧化(Ⅱ)——纳米铜粒子的真空热处理  

CO Oxidation over Nanometer Copper Catalysts Prepared by Physical Method ——Heat Pretreatment to Nanometer Copper in Vacuum

作　　者：杜芳林[1] 陈克正[1] 张志琨[1] 崔作林[1] 

机构地区：[1]青岛化工学院纳米材料研究所,青岛266042

出　　处：《青岛化工学院学报（自然科学版）》2000年第3期192-195,共4页Journal of Qingdao Institute of Chemical Technology(Natural Science Edition)

基　　金：山东省自然科学基金!资助项目 (Y96B0 60 2 5)

摘　　要：用TEM、XRD等方法研究了蒸发法制备的纳米铜真空热处理后粒子尺寸及晶相的变化。将处理后的铜粒子负载于氧化铝上 ,考察了对CO氧化反应的催化活性。结果表明 ,随真空热处理温度的增加 ,纳米铜粒子烧结程度增加 ,尺寸变大 ,催化活性下降 ,晶相也由Cu、CuO变为Cu2 O。TEM and XRD were used to study the changes in particle size and crystal phase of nanometer copper after heat pretreatment in vacuum. The activities for CO oxidation over catalysts supported alumina were studied, in which active component nanometer copper particles were heated in vacuum. The results showed that with the increasing of pretreatment temperature, the sintering degree and particle size of nanometer copper increased, while catalytic activities decreased,and the crystal phase consisting of Cu, CuO changed into Cu_2O.

关 键 词：氧化 纳米铜粒子 热处理 催化剂 物理法 

分 类 号：TB383[一般工业技术—材料科学与工程] TQ131.21[化学工程—无机化工]