自动元素分析仪测定碳纤维中氮、碳、氢  

Determination of Nitrogen,Carbon and Hydrogen in Carbon Fiber with Elemental Analyzer

作　　者：戴俪婧[1] 高敏[1] 张剑锋[1] 王约伯[1] 

机构地区：[1]中国科学院上海有机化学研究所,上海200032

出　　处：《理化检验（化学分册）》2012年第8期926-928,931,共4页Physical Testing and Chemical Analysis(Part B:Chemical Analysis)

摘　　要：利用Vario ELⅢ型元素分析仪测定了碳纤维中氮、碳和氢的含量。优化的试验条件为:称样量2.1～2.4 mg,加氧时间120 s,燃烧管温度980℃。选用乙酰苯胺计算当天校正因子,方法用于碳纤维和石墨样品分析,含碳量在88.05%～99.46%之间,而在绝大多数样品中氮和氢的质量分数都小于0.30%。Contents of nitrogen, carbon and hydrogen in carbon fiber were determined by the Vario EL Ⅲ elemental analyzer. The optimized experimental conditions were as follows： （1） amount of sample： 2.1--2.4 mg; （2） time of oxygen dosing： 120 s; （3） temperature of combustion tube： 980 ℃. Acetanilide was used to calculate the daily factor. The developed method could be applied to samples of carbon fiber and graphite, giving the contents of carbon in the range of 88. 05%-- 99. 46% with less than 0. 30% of nitrogen and hydrogen in most of the samples.

关 键 词：碳纤维 元素分析仪 氮 碳 氢 

分 类 号：O652[理学—分析化学]