YF_3:Nd^(3+)纳米带的制备与性质研究  

Investigation on Fabrication and Properties of YF_3:Nd^(3+) Nanoribbons

作　　者：李剑[1] 谢伟[1] 李楠[1] 马天伦[1] 张博文[1] 于飞[1] 董相廷[1] 

机构地区：[1]长春理工大学化学与环境工程学院,长春130022

出　　处：《长春理工大学学报（自然科学版）》2012年第1期138-140,共3页Journal of Changchun University of Science and Technology(Natural Science Edition)

基　　金：国家自然科学基金项目(50972020;51072026);教育部博士点基金项目(20102216110002)

摘　　要：采用静电纺丝法制备了PVP/[Y(NO3)3+Nd(NO3)3]复合纳米带,将PVP/[Y(NO3)3+Nd(NO3)3]复合纳米带在700℃焙烧8h,获得了Y2O3:Nd3+纳米带。使用NH4HF2为氟化剂,经双坩埚法氟化和脱氨后得到YF3:Nd3+纳米带。XRD分析表明,立方相的Y2O3:Nd3+氟化后,得到了正交相的YF3:Nd3+纳米带,其空间群为Abm2;SEM分析表明,Y2O3:Nd3+纳米带和YF3:Nd3+纳米带宽度分布分别为3.7±0.9μm和3.7±0.7μm,厚度分别为360nm和330nm。PVP/ [Y（NO3）3＋Nd（NO3）3] compositenanoribbons were fabricated by electrospinning technique, the compositenanoribbons were calcined at 700℃ for 8h to prepare Y2O3：Nd3^＋n anoribbons.YF3：Nd^3＋nanoribbons were obtained by fluorination of the relevant Y2O3：Nd^3＋nanoribbons followed by deammoniation process via double-crucible method using NH4HF2 as fluorinating agent.XRD analysis indicate that orthorhombic YF3：Nd3^＋nanoribbons with space group Abm2 were acquired through fluorination of the cubic Y2O3：Nd^3＋nanoribbons.SEM analysis results reveales that the width of Y2O3：Nd3^＋nanoribbons and YF3：Nd^3＋nanoribbons is 3.7±0.9μm and 3.7±0.7μm, respectively, and the thickness of the two kinds ofnanoribbons is 360nm and 330nm, respectively.

关 键 词：静电纺丝 纳米带 YF3:Nd3+ 

分 类 号：O614.33[理学—无机化学]