Copper-Catalyzed Synthesis of Triarylamines from Aryl Halides and Arylamines  

作　　者：钱存卫 许少杰 宗乾收 方东 

机构地区：[1]School of Chemistry and Chemical Engineering,Yancheng Teachers University,Yancheng,Jiangsu 224051 [2]School of Biological and Chemical Engineering,Jiaxing University,Jiaxing,Zhejiang 314001,China

出　　处：《Chinese Journal of Chemistry》2012年第8期1881-1885,共5页中国化学（英文版）

摘　　要：A simple and efficient methodology for the synthesis of triphenylamines has been demonstrated using copper catalyst with a ligand and tripotassium phosphate as the base. The effect of parameters such as catalyst precursors, ligands, bases and solvents were studied and a series of triphenylamines were obtained with moderate to excellent yields in DMF. This reaction displays great functional groups compatibility in the presence of a broad range of functional groups.A simple and efficient methodology for the synthesis of triphenylamines has been demonstrated using copper catalyst with a ligand and tripotassium phosphate as the base. The effect of parameters such as catalyst precursors, ligands, bases and solvents were studied and a series of triphenylamines were obtained with moderate to excellent yields in DMF. This reaction displays great functional groups compatibility in the presence of a broad range of functional groups.

关 键 词：copper catalyst Ullmann coupling triphenylamine SYNTHESIS 

分 类 号：O643.36[理学—物理化学] TQ465[理学—化学]