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作 者:于士平[1] 姚红杰[1] 薛函[1] 范云鸽[1] 施荣富[1]
机构地区:[1]功能高分子材料教育部重点实验室,南开大学高分子化学研究所,天津300071
出 处:《离子交换与吸附》2012年第4期375-384,共10页Ion Exchange and Adsorption
摘 要:简单介绍了离子交换树脂法提取硼的原理,从葡甲胺、多元醇、糖类、邻-二元酚类不同功能基以及聚苯乙烯、聚丙烯酸酯、无机-有机复合型树脂及天然高分子等不同基质材料的角度综述了提硼离子交换树脂的研究现状,认为葡甲胺是目前使用效果最好的功能基化试剂,而基质材料则各有优缺点。同时对硼离子交换树脂在水处理、环境保护、提取分离等领域的应用进行了概括,并对新型提硼树脂的研究进行了展望。This paper introduced the principle of extracting boron with resins. Research status and applications of various types of boron ion exchange resins were summarized, which were stated in terms of functional groups such as polyol, carbohydrate, vicinal-diphenol, as well as matrix materials included polystyrene, polyacrylate, inorganic-organic composite resins, natural polymers and so on. Advantages and disadvantages of these resins were discussed. The paper argues that N-Methyl-D-glucamine works best as the functional reagent. However, each matrix material has its own costs and benefits. A summary of recent information on applications of the boron-specific resins in water treatment and environmental protection, extraction and separation of boron, analysis of boron were provided. The designing trend of novel boron resins were prospected.
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