稀土催化材料的制备、结构及催化性能  

Preparation,structure and catalytic performances of rare earth catalytic materials

作　　者：詹望成[1,2] 郭耘[1,2] 郭杨龙[1,2] 龚学庆[1,2] 王艳芹[1,2] 卢冠忠[1,2] 

机构地区：[1]结构可控先进功能材料及其制备教育部重点实验室 [2]华东理工大学工业催化研究所,上海200237

出　　处：《中国科学：化学》2012年第9期1289-1307,共19页SCIENTIA SINICA Chimica

基　　金：国家重点基础研究发展计划项目(2010CB732300;2004CB719500)资助

摘　　要：稀土催化材料的研究和发展为La和Ce等高丰度轻稀土元素的高质、高效利用提供了有效的途径.稀土元素具有未充满电子的4f轨道和镧系收缩等特征,作为催化剂的活性组分或载体使用时表现出独特的催化性能.本文从稀土氧化物、稀土复合氧化物、稀土-贵金属催化剂、稀土改性多孔催化材料等稀土催化材料出发,重点介绍和讨论了稀土的添加对催化剂的结构、活性和稳定性等的影响,阐述了稀土与过渡金属及氧化物、稀土与贵金属之间的相互作用,及对催化剂催化性能的影响.并对稀土催化材料的研究和发展提出了思考和展望.The research and development of rare earth catalytic materials will greatly promote the high-efficiency utilization of abundant rare earth elements, such as La and Ce. Rare earth elements have under-filled 4f orbits and lanthanide contraction, resulting in their unique catalytic performances when used as an active component or the carrier of catalysts. This paper reviews the progress in the preparation, structural and catalytic properties of rare earth catalytic materials, containing rare earth oxides, rare earth composite oxides, rare earth-noble metal catalysts and rare earth modified porous materials. The effects of rare earth elements on the structures, activities and stabilities of the concerned catalysts are mainly described. As well as, the interactions between rare earth metals and transition metals or noble metals are also elaborated, which are critical for the performances of the catalysts. Finally, the development thinking for rare earth catalytic materials is put forwarded and outlooked.

关 键 词：稀土氧化物 催化材料 氧化还原性能 酸碱性能 催化性能 催化剂制备 

分 类 号：O643.36[理学—物理化学]