SSA分析技术在双向拉伸聚丙烯专用料生产过程中的应用  

Application of SSA analysis technique in biaxially oriented polypropylene specialty resin production

作　　者：刘兴旺[1] 朱宝兴 赵爱利[1] 

机构地区：[1]中国石油兰州石化公司乙烯厂,甘肃兰州730060 [2]中国石油四川乙烯石化公司,四川成都610000

出　　处：《石化技术与应用》2012年第5期436-438,442,共4页Petrochemical Technology & Application

摘　　要：采用连续自成核退火法(SSA)对几种不同双向拉伸聚丙烯(BOPP)树脂进行了等规度及等规序列分布表征,研究了其结晶行为与成膜稳定性之间的关系,据此分析了中国石油兰州石化公司30万t/a聚丙烯装置初期所产BOPP产品在使用过程中存在易破膜问题的原因,并进行了装置聚合工艺参数的优化。结果表明,BOPP树脂的成膜稳定性取决于其等规度分布情况,即高等规度组分含量应较低,低等规度组分含量应较高,峰高比值(IPeak1/IPeak2)以小于1为宜;随着催化剂与外给电子体质量比(T/D)的增大,BOPP树脂的高等规度组分含量逐渐降低,中、低等规度组分含量相对上升,晶片厚度变薄,分布加宽,成膜性能得以改善。The isotacticity and its sequence distri- bution of several biaxially oriented polypropylene （BOPP） specialty resins were characterizated by successive self - nucleation annealing （SSA） meth- od, and the relationship between crystallization and film forming performance was researched. On the ba- sis of this, the cause for film breaking of BOPP resin manufactured in a 300 kt/a polypropylene unit of Lanzhou Petrochemical Company occurred during its extruding was analyzed, and the process parameters of the polymerization were optimized. The results showed that the film forming stability of BOPP resin was dependent on the isotacticity sequence distribu- tion,that was the content of high isotacticity mole- cules needed to be decreased, and the content of low isotacticity molecules needed to be increased. The /Peakl/Ipeak2 ratio should be less than 1. With increas- ing the mass ratio of catalyst to external electron do- nor（T/D） , the content of high isotaeticity moleeules decreased,the content of low and medium isotaetici- ty molecules ineeased,the lamellar became thinner, the isotactieity sequenee distribution became broa- der, and the performanee of film forming was im- proved.

关 键 词：聚丙烯 双向拉伸聚丙烯(BOPP) 等规度 连续自成核退火法(SSA) 差示扫描量热仪 结晶行为 成膜性能 

分 类 号：TQ325.14[化学工程—合成树脂塑料工业]