白光LED用LaPO_4:Eu^(3+)红色荧光粉的合成与表征  

Synthesis and characterization of LaPO_4:Eu^(3+) red phosphor for in white LED application

作　　者：廖金生[1] 周单[1] 杨斌[1] 张骞[1] 周全惠[1] 武淑珍[1] 

机构地区：[1]江西理工大学冶金与化学工程学院,江西赣州341000

出　　处：《有色金属科学与工程》2012年第4期31-35,共5页Nonferrous Metals Science and Engineering

基　　金：国家自然科学基金项目(51162012);国家高技术研究发展计划(863)项目(2010AA03A408);江西省教育厅资助项目(GJJ12327);江西省自然科学基金项目(2010GZW0022);江西理工大学校级科研课题(JXXJ11021)

摘　　要：利用水热法制备了性能稳定的红色荧光粉LaPO4:Eu3+,同时研究了不同的Eu3+浓度、煅烧温度对荧光粉发光性能的影响.通过X射线粉末衍射(XRD)和扫描电子显微镜(SEM)来表征荧光粉的晶体结构和颗粒大小及形貌;用激发光谱和发射光谱以及荧光衰减曲线来表征荧光粉的荧光性能.结果表明:未煅烧时前躯体主要是六方晶相LaPO4·0.5H2O,煅烧温度在900℃时,所制备样品为单斜相LaPO4:Eu3+;SEM图像显示5 at.%Eu3+掺杂LaPO4呈椭球形,颗粒长约为500 nm,宽约为300 nm.最大发射波长和激发波长分别为592 nm和393 nm,发射光谱中592 nm和612 nm的发射峰对应的是Eu3+离子的5D0→7F1和5D0→7F2跃迁.其荧光寿命为3.32 ms.A stable LaPO4：Eu3＋ red phosphor was prepared by hydrothermal method. The influences of the concentration of Eu3＋ and calcination temperature on the luminescent properties were studied. The crystal structure, particle size and morphology were characterized by X-Ray Powder Diffraction （XRD） and Scanning Electron Microscope （SEM） techniques. The luminescent properties of phosphor were measured by emission spectra, excitation spectra and decay curve. The results indicate that the precursors are the LaPO4·0.5H2O crystals of hexagonal without heat-treatment, the as-prepared samples are LaPOa：Eu3＋ crystals of monoclinic phase annealing at 900 ℃, the length of crystal is about 500 nm, the width is about 300 nm. The maximum emission and excitation wavelength are at 592 nm and 393 nm, respectively. The emission peaks at 592 nm and 612 nm are corresponding to 5D0-7F1 and 5D0-7F2 transition of Eu3＋ ions in emission spectrum. The fluorescence lifetime of LaPO4：Eu3＋ phosphor is 3.32 ms.

关 键 词：LED 水热法 LaPO4:Eu3+ 红色荧光粉 

分 类 号：TF845[冶金工程—有色金属冶金] TQ133.2[化学工程—无机化工]