三聚甲醛-裂解焦油C0PNA树脂的合成及其性能研究  

STUDY ON THE SYNTHESIS AND COMPOSITE PROPERTIES OF CONDENSED POLYNUCLEAR AROMATICS RESIN USING PYROLYSIS OIL AS MONOMER AND TRIOXANE AS CROSS-LIN KING AGENT

作　　者：李士斌 石阳阳 王玉伟 张在龙 吴明铂 

机构地区：[1]中国石油大学(华东)重质油国家重点实验室,中国石油大学(华东)理学院,山东青岛266555

出　　处：《炭素》2012年第3期20-24,12,共6页Carbon

基　　金：山东省自然科学基金项目（ZR2011EL030）,中央高校基本科研业务费专项资金项目（27R1210016A）

摘　　要：以裂解焦油为原料，以三聚甲醛为交联剂，在对甲苯磺酸的催化作用下合成缩合多环多核芳香烃（COPNA）树脂。对裂解焦油的基本性质进行了分析，采用FT—IR、1H—NMR和Brown—Ladner法对裂解焦油和COPNA树脂的组成和结构进行了分析，采用TG对比考察了裂解焦油和COPNA树脂的耐热性。研究表明，裂解焦油富含多环芳烃，且不合长链烷基侧链，空间位阻小，适合作为COPNA树脂原料。所制备的COPNA树脂具有较高的耐热性、炭收率和13树脂含量。The condensed polynuclear aromatic （COPNA）resin was synthesized using pyrolysis oil as monomer and trioxane as cross-linking agent in the presence of P-toluene sulfonic acid. The basic properties of pyrolysis oil were studied by FT-IR and 1H-NMR. The critical characteristics of pyrolysis oil and COPNA resin including average molecular structure were obtained by improved Brown-Ladner method on the basis of 1H-NMR analysis. TG was employed to study the thermal behavior of COPNA resin and pyrolysis oil. The results show that pyrolysis oil was supposedly to be desirable reactants to COPNA resin for its high-content aromatics, low content of branched chains, as well as the desirable small steric hindrance. The COPNA resin possesses good thermo-stability, high coke value, and more content of 13 resin.

关 键 词：裂解焦油 三聚甲醛 COPNA树脂 

分 类 号：TQ320.61[化学工程—合成树脂塑料工业]