酞菁金属化合物的合成与应用进展  

Advances in Synthesis and Application of Metal Phthalocyanine Compounds

作　　者：程振华[1] 蔡婷婷[1] 陈际海[1] 周文博[1] 刘咸尚 夏道宏[1] 

机构地区：[1]中国石油大学(华东)重质油国家重点实验室化学工程学院,山东青岛266580

出　　处：《石油化工》2012年第9期1092-1100,共9页Petrochemical Technology

基　　金：山东省自然科学基金项目(2009ZRA05107)

摘　　要：综述了主要涉及铁、钴、镍、铜和锌等过渡金属元素的酞菁金属化合物的研究进展。在单核酞菁金属合成的基础上,目前主要研究双核及多核酞菁金属的合成方法。在酞菁金属的芳环上引入种类不同、数目不同的各种取代基,能大大改善酞菁金属化合物的物理及化学性能,为酞菁金属新材料的应用提供基础。开发酞菁金属化合物的绿色化学合成路线是今后的发展方向。Research progresses in synthesis and application of metal phthalocyanine compounds, which mainly includes transition metals, namely Fe, Co, Ni, Cu and Zn, are introduced. The synthesis methods for dinuclear and polynuclear metal phthalocyanine compounds caught more attention now than that for uninuclear one. It is demonstrated that by the introduction of different kinds and different number of substituent groups to the aromatic rings of phthalocyanines, the physical and chemical properties of the metal phthalocyanine compounds are greatly changed, which is more favorable to the application of these new materials. The review points out that the development of the metal phthalocyanine compounds is trending towards green synthetic routes.

关 键 词：酞菁金属 过渡金属 新材料 

分 类 号：TQ25[化学工程—有机化工]