竹焦油-糠醛热固性树脂的制备及性能表征  

Preparation and Characterization of the Bamboo Tar-furfural Thermosetting Resin

作　　者：王佳讯[1] 贠军贤[1] 陈顺伟[2] 沈绍传[1] 庄晓伟[2] 姚克俭[1] 高云玲[1] 

机构地区：[1]浙江工业大学化学工程与材料学院,浙江杭州310014 [2]浙江省林业科学研究院浙江省森林资源生物与化学利用重点实验室,浙江杭州310023

出　　处：《生物质化学工程》2012年第4期17-21,共5页Biomass Chemical Engineering

基　　金：浙江省与中国林业科学研究院合作项目(2009SY01-3);浙江省森林资源生物与化学利用重点实验室开放基金(无编号)

摘　　要：以竹焦油为原料全部替代苯酚,与糠醛在碱性催化剂作用下,制备了竹焦油-糠醛热固性树脂(BTFF)。随反应时间和反应温度的增加,所制备的BTFF固体含量和黏度增大,游离糠醛含量减小,pH值9～10,密度1.20～1.30 g/mL。根据傅里叶变换红外光谱(FT-IR)分析,BTFF与苯酚-糠醛热固性树脂(PFF)结构相似;经差示扫描量热法分析,BTFF与PFF固化特性相近,固化温度(150℃)较低。Bamboo-tar furfural thermosetting resin （BTFF） was synthesized by bamboo tar and furfural under catalysis of alkaline. The solid content and the viscosity of the BTFF increased, with the increase of reaction temperature and time, while the residue furfural contents reduced. The pH of the prepared BTFF was 9-10, and the density was 1.20-1.30 g/mL. The properties of BTFF were analyzed by Fourier transform infrared spectroscopy （FT-IR） and differential scanning calorimetry （DSC）. The results showed that the chemical structures of BTFF were similar to those of the phenol-furfural resin （PFF）. By DSC, the BTFF was cured at a low temperature （ 150 ℃） which was close to that of PFF.

关 键 词：竹焦油 糠醛 热固性 性能 树脂 

分 类 号：TQ323[化学工程—合成树脂塑料工业]