新型松香基酰基亚胺噻唑烷衍生物的合成  

Synthesis of Novel Rosin-based-acyl-imine-thiazolidine Derivatives

作　　者：伍勇[1,2] 饶小平[2] 王宗德[3] 宋湛谦 

机构地区：[1]四川卫生康复职业学院公共系,四川自贡643000 [2]中国林业科学研究院林产化学工业研究所国家林业局林产化工重点开放性实验室,江苏南京210042 [3]江西农业大学园林与艺术学院,江西南昌330045

出　　处：《合成化学》2012年第5期606-608,共3页Chinese Journal of Synthetic Chemistry

基　　金：国家林业局"林业公益性行业科研专项"(200704008)

摘　　要：以脱氢枞酸或二氢枞酸为起始原料经酰卤化、硫氰酸根加成、有机胺加成异构、浓盐酸催化脱水成环合成了两个新型的松香基酰基亚胺噻唑烷衍生物,产率分别为29%和41.8%,其结构经1H NMR,13C NMR和IR表征。Two novel rosin-based-acyl-imine-thiazolidine derivatives in yields of 29% and 41.8% were synthesized from dehydroabietic acid or dihydroabietic acid by acyl halide reaction,thiocyanate addition reaction,organic amine addition reaction,structural isomerism chemical reaction and catalyzed dehydration of concentrated hydrochloric acid into the ring reaction.The structures were characterized by 1H NMR,13C NMR and IR.

关 键 词：脱氢枞酸 二氢枞酸 酰基亚胺噻唑烷 合成 

分 类 号：O626.2[理学—有机化学]