介孔材料MCM-41催化吲哚与硝基烯Friedel-Crafts反应的研究  

Friedel-Crafts Reaction of Indoles with Nitroalkenes Catalyzed by Mesoporous Material MCM-41

作　　者：陈永诚[1] 谢绍雷[1] 解正峰[1] 

机构地区：[1]新疆大学石油天然气精细化工教育部重点实验室,乌鲁木齐830046

出　　处：《有机化学》2012年第10期1970-1974,共5页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(Nos.20962018;20862015;20562011)资助项目~~

摘　　要：用介孔材料MCM-41催化吲哚与β-硝基烯发生Friedel-Crafts反应,成功地合成了天然产物中广泛存在的3-取代吲哚衍生物.该方法具有反应条件温和、操作简单以及环境友好、经济良好等优点,其催化剂也可循环再用.The Frieldel-Crafts reaction of indole with fl-nitrostyrenes catalyzed by MCM-41 was studied. Application of this reaction led to produce 3-substituted indole derivatives being wide present in natural products. The method has several advan- tages of mild reaction, condition handling-up easily, environmental friendly and economic effects. The catalyst can be also recycled.

关 键 词：介孔材料MCM-41 吲哚衍生物 催化 硝基烯烃 Friedel—Crafts反应 

分 类 号：O626[理学—有机化学]