多铁材料BiFeO_3的制备与表征  

Preparation and Characterization of Multiferroics BiFeO_3

作　　者：宋伟[1,2,3] 王暄[1,2,3] 张冬[1,2,3] 孙志[1,2,3] 韩柏[1,2,3] 何丽娟[2,3] 雷清泉[1,2,3] 

机构地区：[1]哈尔滨理工大学电气与电子工程学院,哈尔滨150080 [2]工程电介质及其应用技术教育部重点实验室,哈尔滨150080 [3]黑龙江省电介质工程重点实验室,哈尔滨150080

出　　处：《无机材料学报》2012年第10期1053-1057,共5页Journal of Inorganic Materials

基　　金：国家重点基础研究发展计划(973计划)(2009CB724505;2012CB723308);国家自然科学基金(5097702)~~

摘　　要：以硝酸铁和硝酸铋为反应物,柠檬酸为络合剂,硝酸为催化剂,采用柠檬酸溶胶–凝胶法制备粒径分布均匀的多铁性材料BiFeO3纳米粉体,通过TG-DSC、XRD、FT-IR、SEM及AFM等手段对样品的结构、形貌及纯净度进行表征.研究结果表明,在溶胶过程中前驱液的pH值以及干凝胶的煅烧温度等合成条件对BiFeO3纳米粉体的制备和纯净程度都有一定的影响,最佳的合成条件是前驱溶液的pH=7～8,干凝胶的煅烧温度为600℃.在该条件下得到的BiFeO3纳米粉体中无杂相Bi25FeO40和Bi2Fe4O9等,纳米颗粒尺寸在100 nm左右,分散性良好,饱和磁化强度Ms=1.08 A·m2/kg,剩余磁化强度Mr=0.13 A·m2/kg,矫顽力Hc=15.76 kA/m.The multiferroic materials BiFeO3 nanopowders of dispersion uniformity were synthesized by the citric acid Sol-Gel method,using the iron（Ⅲ） nitrate and bismuth nitrate as the reactants and dilute nitric acid as the catalyst. The physical and chemical characteristics,such as structure,morphology and purity of BiFeO3 nanopowders were investigated by TG-DSC,XRD,FT-IR,SEM and AFM,respectively.The results indicate that the preparation and purity of BiFeO3 nanopowders have a profound influence on the precursor solution pH value of sol process and the calcined temperature of the xerogel.The optimum reaction conditions are the precursor solution pH=7–8 and calcined temperature of 600℃.It is found that BiFeO3 nanopowders with 100 nm in size,good dispersion and without Bi25FeO40 and Bi2Fe4O9 impurity phase are synthesized under the optimum reaction conditions.The saturation magnetization（Ms）,the remanent magnetization（Mr） and the coercivity（Hc） of BiFeO3 nanopowders under the optimum reaction conditions are 1.08 A·m2/kg,0.13 A·m2/kg and 15.76 kA/m,respectively.

关 键 词：多铁性材料 铁酸铋 溶胶–凝胶 纳米粉体 

分 类 号：TQ174[化学工程—陶瓷工业]