煤系高岭土酸浸脱铝水热合成NaY分子筛  

Hydrothermal synthesis of NaY molecular sieve from coal-series kaolin by acid-leaching dealuminization

作　　者：蒋荣立[1] 陈文龙[1] 赵锐先[1] 王茜[1] 

机构地区：[1]中国矿业大学化工学院煤炭加工与高效洁净利用教育部重点实验室,江苏徐州221116

出　　处：《中国矿业大学学报》2012年第5期811-816,共6页Journal of China University of Mining & Technology

基　　金：中央高校基本科研业务费专项资金项目(2010LKHX05)

摘　　要：以煤系高岭土为原料,经煅烧、酸浸脱铝工艺,首次在酸浸偏高岭土-碱水热反应体系中合成了NaY分子筛.采用XRD,SEM对所合成样品进行表征,考察了体系中碱度、硅铝比、老化过程、晶化过程对NaY分子筛合成的影响.结果表明:该水热反应体系适宜的碱度条件为n(H2O)/n(Na2O)=80,碱度过高或过低均会出现P型分子筛杂相.适宜的硅铝配比为n(SiO2)/n(Al2O3)=6.4;老化有助于生成纯相、结晶度好的NaY分子筛,其适宜的老化温度为50℃、老化时间为4h.晶化温度过高或晶化时间过长易转晶生成P型杂相,适宜的晶化条件是晶化温度为85℃、晶化时间为24h.在该反应体系中反应原料由偏高岭土酸浸脱铝后获得,产物结晶度较高,无杂晶,晶形完整,粒度为2μm左右.Taking coal-series kaolin as the material, the high-silica NaY molecular sieve was synthesized firstly in the hydrothermal reaction system of acid-leaching metakaolinite-alkali af- ter calcination and acid-leaching processes. The product was charactered by XRD and SEM. The effects of various hydrothermal conditions, including the molar ratios of n（SiO2）/ n（A12O3）, aging process and crystallizing process on NaY molecular sieve synthesizing were in- vestigated. The results show that the proper alkalinity condition is molar ratios n（H20）/ n（Na2O）=80. The higher or lower alkalinity will cause molecular sieve impurity phase. The optimum n（SiO2）/n（A12O3） is 6.4. Theaging process contributes to generate pure and good crystallinity NaY molecular sieve, and the proper aging temperature and time are 50 ℃ and 4 h, respectively. The higher crystallizing temperature or longer crystallizing time will easily cause crystal transformation and yield P molecular sieve impurity phase. The proper crystalli- zing temperature and time are 85 ℃ and 24 h, respectively. The reaction material is easily yiel- ded by acid-leaching only once and the 2/μm synthesized NaY zeolites are of a higher crystallini- ty and excluding impure crystals.

关 键 词：酸浸 煤系高岭土 水热合成 NAY分子筛 

分 类 号：TQ072[化学工程]