二水合硫酸钙晶须制备研究  

Research on Preparation of Dihydrate Calcium Sulfate Whisker

作　　者：李方艳[1] 朱伟长[1] 徐兰[1] 

机构地区：[1]安徽工业大学材料科学与工程学院安徽省金属材料与加工重点实验室,安徽马鞍山243002

出　　处：《安徽工业大学学报（自然科学版）》2012年第4期335-337,共3页Journal of Anhui University of Technology（Natural Science）

基　　金：安徽省教育厅自然科学研究重点项目(KJ2008A003)

摘　　要：盐酸溶解碳酸钙并加入适量的表面活性剂。再加入稀硫酸在常温下生成二水合硫酸钙晶须，反应后滤液为盐酸溶液，再次加入碳酸钙后可循环使用。考察反应系统中表面活性剂浓度、Ca2＋浓度、硫酸等对晶须形貌的影响。结果表明，最佳工艺条件为Ca2＋浓度0．3mol／L，十二烷基磷酸酯钾质量浓度5．0g／L，壬基酚聚环氧乙烯醚质量浓度2．5g／L，硫酸浓度0．28mol/L。晶须长2-200μm，长径比30-100。Dihydratc calcium sulfate whisker is produced when calcium carbonate is dissolved with hydrochloric acid, then an appropriate amount of surfactant and dilute sulfuric acid are added at room temperature. After the reaction, hydrochloric acid solution as the filtrate can be recycled when calcium carbonate is added again. Effects of surfactant concentration, Ca2＋ concentration, and sulfuric acid concentration in the reaction system on whisker morphology are studied. Results show that optimum conditions of preparation are as follows： Ca2＋ concentration is 0.3 mol/L, concentration of twelve potassium alkyl phosphate is 5.0 g/L, concentration of nonylphenol polyethylene vinyl is 2.5 g/L, and concentration of H2SO4 is 0.28 mol/L. Gypsum whisker obtained is of 20-200 μm in length with length-diameter ratio of 30-100.

关 键 词：二水硫酸钙 制备工艺 晶须 

分 类 号：TB321[一般工业技术—材料科学与工程]