Mechanistic aspects of oxidation of palladium with O_2  

作　　者：JIN LiQun LEI AiWen 

机构地区：[1]College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,China

出　　处：《Science China Chemistry》2012年第10期2027-2035,共9页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China (21025206, 20832003, and 20972118);the National Basic Research Program of China, 973 Program (2012CB725302);Academic Award for Excellent Ph.D. Candidates Funded by Ministry of Education of China

摘　　要：Palladium-catalyzed aerobic transformation has been one of the most challenging topics within organometallics chemistry. Recently, the corresponding methodology has been developed rapidly, involving alcohol oxidation, alkene oxidation, oxidative coupling and so on, which stimulated considerable interests in mechanistic investigation of the oxidation of Pd with O2 . This review summarizes most of the mechanistic studies on this topic during the past ten years. Moreover, the future of the mechanistic investigation for aerobic oxidation of Pd is also discussed.Palladium-catalyzed aerobic transformation has been one of the most challenging topics within organometallics chemistry. Recently, the corresponding methodology has been developed rapidly, involving alcohol oxidation, alkene oxidation, oxidative coupling and so on, which stimulated considerable interests in mechanistic investigation of the oxidation of Pd with O2 . This review summarizes most of the mechanistic studies on this topic during the past ten years. Moreover, the future of the mechanistic investigation for aerobic oxidation of Pd is also discussed.

关 键 词：PALLADIUM O2 MECHANISM 

分 类 号：O643.12[理学—物理化学] O643.36[理学—化学]