第三主族金属簇合物  

Group 13 Metal Cluster Compounds

作　　者：孙洁[1] 孟令鹏[1] 郑世钧[1] 李晓艳[1] 

机构地区：[1]河北师范大学化学与材料科学学院,石家庄050016

出　　处：《化学通报》2012年第10期893-896,共4页Chemistry

基　　金：国家自然科学基金项目(20973053;21073051;2112033;21171047);河北省自然科学基金项目(B2010000371;B2011205058);河北省教育厅基金项目(ZD2010126)资助

摘　　要：金属簇合物化学是在金属有机化学与无机配合物化学基础上发展起来的一门新兴学科。第ⅢA族元素由于其缺电子特性而备受关注,大量以前认为不存在的、具有双键或叁键的第三主族金属簇合物分子相继被合成,并且通过X射线衍射和光谱学分析得到了它们的结构和性质。本文介绍了第ⅢA族金属簇合物的实验及理论研究进展,同时也提出了一些需要深入解决的新问题。The metal cluster compounds chemistry is a new branch which developed on the basis of organometallic chemistry and inorganic complexes chemistry. Owing to their electron deficient nature, the group 13 elements are attracted more and more attention. So far numerous molecules containing double or triple bonds which were previously thought unable to exist have been synthesized, and their structure and properties have been characterized by X-ray structural analyses and spectroscopic measurements. In this paper, the progress of the experimental and theoretical researches of metal cluster compounds containing group 13 elements were introduced, and some questions that need further research arc presented.

关 键 词：金属簇合物 第三主族元素 金属-金属键 

分 类 号：O621.2[理学—有机化学]