Investigations into thermoluminescence and afterglow characterization of strontium aluminates with boron-modification and reductions via sol-gel route  

作　　者：陈一诚 陈克恭 陈弘森 杜哲光 林昭任 林秀雄 陈登铭 谢天渝 

机构地区：[1]Material Applications Center/IS,Industrial Technology Research Institute [2]College of Dental Medicine,Kaohsiung Medical University [3]Chemical Engineering Department,National Chung-Cheng University [4]Orthodontic Division,Department of Dentistry,Kaohsiung Chang Gung Memorial Hospital and Chang Gung University College of Medicine [5]Applied Chemistry Department,National Chiao Tung University

出　　处：《Journal of Rare Earths》2012年第10期972-978,共7页稀土学报（英文版）

基　　金：Project supported by Industrial Technology Research Institute

摘　　要：The effects of strontium aluminates of SrAl2O4：Eu2＋,Dy3＋（SAED） and boron-modified SAED （BSAED） phases synthesized from a sol-gel process on thermoluminescence （TL） along with their afterglow properties were systematically investigated with thermal activation in the different atmospheres. The result showed that the addition of boron and the reduction routes of Eu3＋to Eu2＋ in SrAl2O4：Dy3＋were related to phosphorescent decay properties. The aid of Dy3＋to induce the hole-trapping effect required both SAED and BSAED to be heated at 1300°C under the H2/N2（5%：95%） atmosphere. However, the trapping behavior of the reductions of SAED in nitrogen was similar to the compound without Dy3＋co-doping SrAl2O4：Eu2＋ （SAE） in H2/N2（5%：95%）. BSAED showed deeper traps in situ compared to SAED which contained no boron, and this led to the better afterglow properties of BSAED than those of SAED. The afterglow spectrum of BSAED showed two peaks at 400±1 nm and 485±1 nm, which were two individuals composed and contributed from different depths of traps at 0.57 and 0.76eV, accordingly. The depth of the traps was calculated from the Hoogenstraaten’s plot of glow curves. The calculations for SAED and SAE were at around 0.43 and 0.18eV, respectively.The effects of strontium aluminates of SrAl2O4：Eu2＋,Dy3＋（SAED） and boron-modified SAED （BSAED） phases synthesized from a sol-gel process on thermoluminescence （TL） along with their afterglow properties were systematically investigated with thermal activation in the different atmospheres. The result showed that the addition of boron and the reduction routes of Eu3＋to Eu2＋ in SrAl2O4：Dy3＋were related to phosphorescent decay properties. The aid of Dy3＋to induce the hole-trapping effect required both SAED and BSAED to be heated at 1300°C under the H2/N2（5%：95%） atmosphere. However, the trapping behavior of the reductions of SAED in nitrogen was similar to the compound without Dy3＋co-doping SrAl2O4：Eu2＋ （SAE） in H2/N2（5%：95%）. BSAED showed deeper traps in situ compared to SAED which contained no boron, and this led to the better afterglow properties of BSAED than those of SAED. The afterglow spectrum of BSAED showed two peaks at 400±1 nm and 485±1 nm, which were two individuals composed and contributed from different depths of traps at 0.57 and 0.76eV, accordingly. The depth of the traps was calculated from the Hoogenstraaten’s plot of glow curves. The calculations for SAED and SAE were at around 0.43 and 0.18eV, respectively.

关 键 词：SrAl2O4：Eu2＋ Dy3＋ boron addition long afterglow THERMOLUMINESCENCE decay constant trap depth rare earths 

分 类 号：O611.4[理学—无机化学]