(Z)-3-(4-氯苯基)-3-[N,N-二-(4-氯-1-甲基-3-乙基-5-吡唑甲酰基)-氨基]-2-氰基丙烯酸乙酯的合成  

Synethesis of(Z)-3-(4-chlorophenyl)-3-[N,N-di-(4-chloro-3-ethyl-1-methy-5-pyrazole formyl)-amino]-2-ethyl cyanoacrylates

作　　者：张德华[1] 郑静[1] 

机构地区：[1]湖北师范学院化学与环境工程学院,湖北黄石435002

出　　处：《湖北师范学院学报（自然科学版）》2012年第3期63-65,共3页Journal of Hubei Normal University(Natural Science)

基　　金：湖北省教育厅优秀中青年项目资助(D20112503)

摘　　要：以对氯苯甲酰氯与氰基乙酸乙酯反应,经氯化,氨化,再与4-氯-1-甲基-3-乙基-5-吡唑甲酰氯反应,合成了(Z)-3-(4-氯苯基)-3-[N,N-二-(4-氯-1-甲基-3-乙基-5-吡唑甲酰基)-氨基]-2-氰基丙烯酸乙酯,其结构经1H NMR,IR,X晶体衍射分析,证实为目标化合物。（Z）-3-（4-chlorophenyl）-3-[N,N-di-（4-chloro-3-ethyl-1-methy-5-pyrazole formyl）-amino]-2-ethyl cyanoacrylates was prepared from 4-chlorobenzoyl chloride and ethyl 2-cyanoacetate,by chlorination and ammoniation.afterw-ards the reaction with 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carbonyl chloride.The structures were confirmed by 1H NMR,IR and X-ray crystallography,It was proved to be the target compounds.

关 键 词：氰基丙烯酸乙酯 合成 晶体结构 

分 类 号：O625.463[理学—有机化学]