Iron（lll）-Catalyzed Direct N-Alkylation of Azoles via Oxidative Transformation of sp3 C H Bonds under Solvent-Free Conditions  

作　　者：刘湘 陈永欣 李康宁 王东 陈保华 

机构地区：[1]State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou,Gansu 730000,China [2]Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province,Lanzhou,Gansu 730000,China

出　　处：《Chinese Journal of Chemistry》2012年第10期2285-2291,共7页中国化学（英文版）

基　　金：We are grateful for the support of this project from the Scientific Research Foundation of the State Educa- tion Ministry （No. 107108） and the National Natural Science Foundation of China （No. J0730425）.

摘　　要：A new approach to synthesize N-alkylation of azoles by iron（III）-catalyst under solvent-free conditions was de- veloped. The method is broad in scope and highly efficient.A new approach to synthesize N-alkylation of azoles by iron（III）-catalyst under solvent-free conditions was de- veloped. The method is broad in scope and highly efficient.

关 键 词：AZOLES N-ALKYLATION SOLVENT-FREE iron catalyst C--H activation 

分 类 号：O614.811[理学—无机化学] TQ460.4[理学—化学]