Highly Efficient C--N Bond Forming Reactions in Water Catalyzed by Copper（I） Iodide with Calix[4]arene Supported Amino Acid Ionic Liquid  

作　　者：黄利 金灿 苏为科 

机构地区：[1]Key Laboratory of Green Pharmaceutical Technologies and Related Equipment of Ministry of Education,College of Pharmaceutical Sciences,Zhejiang University of Teehnology,Hangzhou,Zhejiang 310014,China

出　　处：《Chinese Journal of Chemistry》2012年第10期2394-2400,共7页中国化学（英文版）

基　　金：We gratefully acknowledge financial support from the National Natural Science Foundation of China （No. 21176222）.

摘　　要：A novel and effective protocol has been developed for the Ullmann-type C--N coupling reaction catalyzed by calix[4]arene supported amino acid ionic liquid and copper（I） iodide in water under microwave irradiation condition The protocol uses ealix[4]arene supported amino acid ionic liquid as double function of the ligand and phase-transfer catalyst, and shows good tolerance in good to excellent yields.A novel and effective protocol has been developed for the Ullmann-type C--N coupling reaction catalyzed by calix[4]arene supported amino acid ionic liquid and copper（I） iodide in water under microwave irradiation condition The protocol uses ealix[4]arene supported amino acid ionic liquid as double function of the ligand and phase-transfer catalyst, and shows good tolerance in good to excellent yields.

关 键 词：arene supported ionic liquid copper（I） iodide surfactant CROSS-COUPLING microwave irradia-tion 

分 类 号：TQ424.1[化学工程] O625.1[理学—有机化学]