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出 处:《Journal of Rare Earths》2012年第11期1142-1145,共4页稀土学报(英文版)
基 金:Project supported by National Basic Research Program of China (2012CBA01206);National Natural Science Foundation of China (51074148,51222404,91026024)
摘 要:A calixarene derivative, 5,11,17,23-tetra(diethoxyphosphoryl)-25,26,27,28-tetraacetoxycalix[4]arene (L), was studied for the extraction and separation of thorium and rare earths in nitrate medium. Thorium was extracted into the organic phase by a complex of Th(NO3)4·L with the logarithm of the equilibrium constant of 2.77. Thermodynamic functions, AH, AG and AS were calculated to be -2.49, -15.55 kJ/mol and 44.53 J/(mol·K), respectively. The results indicated that this calixarene derivative might be used to separate thorium from rare earths and the separation factors were larger than 26. However, the salting-out agents affected the separation.A calixarene derivative, 5,11,17,23-tetra(diethoxyphosphoryl)-25,26,27,28-tetraacetoxycalix[4]arene (L), was studied for the extraction and separation of thorium and rare earths in nitrate medium. Thorium was extracted into the organic phase by a complex of Th(NO3)4·L with the logarithm of the equilibrium constant of 2.77. Thermodynamic functions, AH, AG and AS were calculated to be -2.49, -15.55 kJ/mol and 44.53 J/(mol·K), respectively. The results indicated that this calixarene derivative might be used to separate thorium from rare earths and the separation factors were larger than 26. However, the salting-out agents affected the separation.
关 键 词:THORIUM rare earths phosphorylated calixarene solvent extraction
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