5-羟甲基糠醛的制备及其催化氧化研究进展  

Progress in Synthesis of 5-Hydroxymethylfuraldehyde and Its Catalytic Oxidation

作　　者：徐杰[1] 马继平[1,2] 马红[1] 

机构地区：[1]中国科学院大连化学物理研究所洁净能源国家实验室催化基础国家重点实验室,辽宁大连116023 [2]中国科学院研究生院,北京100049

出　　处：《石油化工》2012年第11期1225-1233,共9页Petrochemical Technology

摘　　要：综述了生物质基平台化合物5-羟甲基糠醛(HMF)的制备及其催化氧化研究进展。分析了果糖、葡萄糖、纤维素等碳水化合物制备HMF面临的挑战和解决方法。讨论了HMF氧化产品2,5-二甲酰基呋喃、2,5-呋喃二甲酸的催化合成及其应用。指出纤维素是碳水化合物脱水制备HMF的最终目标底物,并对纤维素制备HMF的研究及其催化氧化发展前景进行了分析。Progresses in the synthesis of bio-derived platform compound 5-hydroxymemylIurtura （HMF） and its catalytic oxidation are reviewed. The existing problems in the synthesis of HMF from different carbohydrates, such as fructose, glucose and cellulose are analyzed, and the resolvents are discussed. The products of the HMF catalytic oxidation, namely 2, 5-diformylfuran and 2, 5-furandicarboxylic acid, and their applications are summarized. It is proposed that cellulose is the ultimate substrate for the dehydration of carbohydrates to HMF. The prospect for the catalytic oxidation of HMF is also analyzed.

关 键 词：5-羟甲基糠醛 2  5-二甲酰基呋喃 2  5-呋喃二甲酸 呋喃基聚合物 纤维素 催化氧化 

分 类 号：TQ224[化学工程—有机化工]