黏胶纤维用落叶松溶解浆的清洁漂白  

Clean bleaching of larch dissolving pulp used for viscose fiber

作　　者：徐峻[1] 李智[1] 李军[1] 莫立焕[1] 陈克复[1] 

机构地区：[1]华南理工大学制浆造纸工程国家重点实验室,华南理工大学植物资源化学与化工联合实验室,广东广州510640

出　　处：《化工学报》2012年第12期4062-4067,共6页CIESC Journal

基　　金：国家重点基础研究发展计划项目(2010CB732205);2010年华南理工大学制浆造纸工程国家重点实验室青年创新基金~~

摘　　要：引言近年来,随着棉花价格的总体上涨和消费者对纺织材料舒适度的要求,给黏胶纤维带来了需求增长空间。作为黏胶纤维的原材料,国内目前的溶解浆产能难以满足客户需求。据统计。Two-stage oxygen delignification（O1/O2）and chlorine dioxide-based bleaching sequence（D0ED1P,where D was chlorine dioxide bleaching,E alkaline extraction and P hydrogen peroxide bleaching）was employed to bleach pre-hydrolyzed larch kraft pulp.The dosage effect of sodium hydroxide（NaOH）in O1 stage,chlorine dioxide（ClO2）in D0 one and hydrogen peroxide（H2O2）in P one on pulp properties was investigated.The results showed that high efficiency of oxygen delignification can be achieved in two-stage delignification,and the Kappa reduction of 76.4% was gained at optimal amount 2.5% and 0.5% NaOH in O1 and in O2 stages respectively.The dissolving pulp with alpha cellulose 94.1%,pentosan 2.86%,polymerization degree 511 and ISO brightness 87.2% can be prepared by D0ED1P bleaching for the oxygen-delignification pulp at optimal chemicals dosage.It has been proved that the bleaching technology proposed in this paper is reliable.The clean bleaching sequence could be used to remake the traditional CEHP bleaching（C chlorine,E alkaline extraction,H hypochlorite and P hydrogen peroxide bleaching）with the advantage of investment saving due to reuse of original apparatus and pipelines.In addition,the content of absorbable organic halides（AOX）generated during bleaching was just 0.96 kg·（t pulp）-1,only about ten percent of the AOX generated in traditional CEHP bleaching,giving better environmental benefit.

关 键 词：黏胶纤维 落叶松 溶解浆 清洁漂白 AOX 

分 类 号：TS745[轻工技术与工程—制浆造纸工程]