全生物基非异氰酸酯聚氨酯的制备与性能  

Preparation and properties of all-bio-based non-isocyanate polyurethane

作　　者：王朝[1] 张星[1] 陈佳佳[1] 母雅丹[1] 黄兆辉[1] 周舟[1] 张立群[1,2] 

机构地区：[1]北京化工大学有机无机复合材料国家重点实验室,北京100029 [2]北京化工大学北京市新型高分子材料制备与加工重点实验室,北京100029

出　　处：《合成橡胶工业》2012年第6期425-428,共4页China Synthetic Rubber Industry

基　　金：国家自然科学基金资助项目(50933001);国家杰出青年科学基金资助项目(50725310);北京市自然基金面上项目(2102020)

摘　　要：通过环氧大豆油与二氧化碳催化加成反应制得五元环碳酸酯,然后与1,10-癸二胺进行开环反应制备了全生物基非异氰酸酯聚氨酯(NIPU)预聚物,考察了预聚反应条件,并根据该条件直接压片制得NIPU弹性体,研究了NIPU弹性体的性能。结果表明,预聚反应最适宜条件为温度120℃、五元环碳酸酯官能团与胺基的摩尔比约1∶1;NIPU弹性体的玻璃化转变温度为-5℃,拉伸强度为1.8 MPa。Carbonated soybean oil（CSBO） was prepared by catalytic addition reaction of epoxidized soybean oil and carbon dioxide,then the all-bio-based non-isocyanate polyurethane（NIPU） prepolymers were synthesized with CSBO and 1,10-decanediamine using a ring-opening method.The optimum reaction conditions were investigated,the NIPU elastomer was prepared by directly tabletting according to the conditions,and the properties of NIPU elastomer were studied.The results showed that the best reaction temperature was 120 ℃ and the best mole ratio of carbonic ester group to amine group was about 1∶ 1.The glass transition temperature of NIPU elastomer was about-5 ℃ and tensile strength was 1.8 MPa.

关 键 词：环氧大豆油 五元环碳酸酯 1 10-癸二胺 生物基 非异氰酸酯聚氨酯 预聚物 弹性体 玻璃化转变温度 

分 类 号：TQ323.8[化学工程—合成树脂塑料工业]