超薄铝/碳酸锂修饰氧化铟锡阴极制备蓝色磷光反转底发光有机发光二极管  

Ultrathin Al/Li_2CO_3 Modified Indium Tin Oxide Cathode for Blue Phosphorescent Inverted Bottom-emission Organic Light-emitting Diodes

作　　者：史常生[1] 陈江山[1] 马东阁[1] 

机构地区：[1]中国科学院长春应用化学研究所,长春130022

出　　处：《应用化学》2012年第12期1412-1416,共5页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金资助项目(60906020)

摘　　要：在氧化铟锡(ITO)阴极上依次蒸镀2 nm铝和2 nm碳酸锂(Li2CO3)薄膜作为电子注入层,成功制备出器件结构为ITO/Al/Li2CO3/SPPO13/SPPO13∶FIrpic/TCTA/MoO3/Al(SPPO13:2,7-双(二苯基磷)-9,9'-螺二[芴];FIrpic:双(4,6-二氟苯基吡啶-N,C2)吡啶甲酰合铱;TCTA:4,4',4″-三(咔唑-9-基)三苯胺)的蓝色磷光反转底发光有机发光二极管(IBOLED)。结果表明,Al/Li2CO3作为电子注入层可以有效降低ITO与有机材料之间的电子注入势垒,蓝色磷光IBOLED的起亮电压由11 V降至4.2 V,器件的发光效率也得到有效提高。蓝光磷光IBOLED的最大电流效率与功率效率分别达到了28.2 cd/A和19.6 lm/W,制备出的反转结构器件性能可与传统正置结构比美,说明Al/Li2CO3可以作为反转有机发光二极管优良的电子注入层。Efficient blue phosphorescent inverted bottom-emission organic light-emitting diode（IBOLED） based on indium tin oxide（ITO） cathode has been successfully fabricated by thermal evaporation using Al（2 nm）/Li2CO3（2 nm） as the electron-injection layer.The structure of this device is ITO/Al/Li2CO3/SPPO13/SPPO13∶ FIrpic/TCTA/MoO3/Al（SPPO13：2,7-bis（diphenylphosphoryl）-9,9′-spirobi[fluorene];FIrpic：bis（4,6-difluorophenylpyridinato-N,C2）picolinatoiridium;TCTA：4,4′,4″-tri（9-carbazoyl）triphenylamine）.It is found that the electron injection barrier between ITO and the organic layer can be significantly reduced with the presence of Al/Li2CO3,leading to the reduction of the turn-on voltage from 11 V to 4.2 V and the significant enhancement of efficiencies.The inverted device exhibits a maximum current efficiency of 28.2 cd/A and a maximum power efficiency of 19.6 lm/W,which are comparable with the conventional device.This suggests that Al/Li2CO3 has the potential to be used as the electron injection layer for inverted OLEDs.

关 键 词：有机发光二极管 反转底发光 电子注入层 氧化铟锡阴极 

分 类 号：O649[理学—物理化学] TN837.3[理学—化学]