1-氨基-2-(2’-甲基-4’-丙酸甲酯)苯氧基-4-羟基蒽醌的合成  

Synthesis of 1 - Amino - 2 - (2' - Methyl - 4' - Methyl Propionate) Phenoxy - 4 - Hydroxy Anthraquinone

作　　者：胡莹玉[1] 李红斌 孙灵[2] 沈永嘉[2] 邱忠成 

机构地区：[1]上海大学环境与建筑工程学院,上海200072 [2]华东理工大学精细化工研究所,上海200237 [3]上海分析仪器总厂,上海200233

出　　处：《有机化学》2000年第4期533-536,共4页Chinese Journal of Organic Chemistry

摘　　要：邻甲苯酚与丙烯腈经Friedel-Crafts反应得到了2-甲基-4-β-氰基乙基苯酚,其与1-氨基-2-溴-4-羟基蒽醌经亲核取代形成的产物经水解、酯化得到目标化合物。给出了该化合物及其中间体的质谱、核磁共振氢谱、元素分析、可见光谱及熔点等数据。2 - Methyl - 4 - B - cyanoethylphenol was synthesized via Friedel - Crafts reaction between o - cresol and acrylonitrile. It was condensed with 1 - amino - 2 - bromo - 4 - hydroxy anthraquinone by the nucleophilic reaction. The product was hydrolyzed in alkaline medium and esterified with methanol to afford the title compound . Mass , H NMR, element analyses, Vis spectra and the melting points of the title compound and the intermediates were measured .

关 键 词：邻甲苯酚 丙烯腈 蒽酯 合成 染料 

分 类 号：O625[理学—有机化学]