(E,E)-3,7-二甲基-2,6-癸二烯-1,10-二醇的高立体选择性合成  

Highly Stereoselective Synthesis of (E,E)- 3,7-Dimethyl-2,6- decadiene-1,10-diol

作　　者：刘佐胜[1] 兰炯[1] 彭立增[1] 李裕林[1] 邢雅成[2] 岑文[2] 

机构地区：[1]兰州大学应用有机化学国家重点实验室,有机化学研究所兰州730000 [2]青岛大学化工系,青岛266071

出　　处：《高等学校化学学报》2000年第8期1237-1239,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金! (批准号 :2 9672 0 15 )

摘　　要：E,E) 3,7 Dimethyl 2,6 decadiene 1,10 diol(3), a terpenoid diol component of pheromonal secretion of the male queen butterfly, was synthesized stereoselectively from geraniol in seven steps. The key steps were the iodization rearrangement of 2,3 epoxy alcohol 6 and Claisen rearrangement of allyl vinyl ether 8.E,E) 3,7 Dimethyl 2,6 decadiene 1,10 diol(3), a terpenoid diol component of pheromonal secretion of the male queen butterfly, was synthesized stereoselectively from geraniol in seven steps. The key steps were the iodization rearrangement of 2,3 epoxy alcohol 6 and Claisen rearrangement of allyl vinyl ether 8.

关 键 词：2 3-环氧醇 碘代重排 克莱森重排 合成 二元醇 

分 类 号：O623.413[理学—有机化学]