碱土掺杂硅酸镧电解质材料的制备与性能  

Preparation and performance of Lanthanum silicate electrolyte materials doped alkali earth

作　　者：黄志良[1] 鲁冕[1] 石月[1] 詹刚[1] 陈巧巧[1] 吴博[1] 陈亚男[1] 池汝安[2] 

机构地区：[1]武汉工程大学材料科学与工程学院,湖北武汉430074 [2]武汉工程大学化工与制药学院,湖北武汉430074

出　　处：《武汉工程大学学报》2012年第11期44-49,共6页Journal of Wuhan Institute of Technology

基　　金：湖北省自然科学重点基金(No.2011CDA050);国家973预研项目(No.2011CB411901);教育部长江学者与创新团队项目(No.IRT974)

摘　　要：采用尿素-硝酸盐燃烧法在600～800℃下制备了较高纯度无杂质相的碱土掺杂磷灰石型La9.33Mx(SiO4)6O2+δ(M为Sr,Ca,Mg)电解质.通过X射线衍射、扫描电镜和交流阻抗测试,对样品的晶体结构、表面微观形貌及电导性能进行了研究.结果表明,燃烧合成的电解质粉体La9.33(SiO4)6O2(LSO)具有p63/m磷灰石型晶体结构;LSO烧结体的微观形貌随x值的不同而出现了细微变化;LSO烧结体具有良好的电阻可逆性和稳定性.适当的掺杂量能有效提高LSO的离子电导率,最佳掺杂浓度为0.2.相同掺杂量下,三种碱土金属阳离子掺杂对电导性能也有一定的影响,随着离子半径的增大,掺杂效果越来越好.The urea-nitrates combustion was introduced to prepare the high purity apatite type alkali earth doped La9.33 Mx （SiO4）6 O2＋ （M are Sr, Ca and Mg） conductor at 600-- 800℃. The as-prepared samples were investigated by X-Ray Diffraction, Scanning Electron Microscope and Electrochemical Impedance Spectroscopy. The results show that the powders transform into p6a/m apatite-type after burning. The microcosmic appearance of sintered LSO is altered with the different doping content x. LSO sintered body possesses excellent resistors reversibility and stability. The conductivity is improved efficiently with the doping amounts of the alkali earth metal ions, and the optimal doping content is 0.2. Under the same doping contents, three kinds of alkali earth metal ions also have effects on the anductivity performance. As the ionic radius increases, doping effect becomes better.

关 键 词：磷灰石型固体电解质 硅酸镧 碱土掺杂 燃烧法 电导率 

分 类 号：TM911[电气工程—电力电子与电力传动] Q611.4[生物学—生物物理学]