傅里叶红外光谱法研究GAP/AP混合体系的快速热裂解  

An Investigation of Fast Thermolysis of GAP/AP System by FTIR Spectroscopy

作　　者：张腊莹[1] 刘子如[1] 王晓红[1] 衡淑云[1] 邵颖慧[1] 丁黎[1] 

机构地区：[1]西安近代化学研究所火炸药燃烧国防科技重点实验室,陕西西安710065

出　　处：《光谱学与光谱分析》2013年第1期14-18,共5页Spectroscopy and Spectral Analysis

基　　金：国防科技重点实验室基金项目(9140C3505030708)资助

摘　　要：用T-Jump/FTIR在线联用分析技术,研究了GAP/AP混合体系在模拟燃烧条件下快速加热高温高压的热裂解。结果表明,GAP/AP混合体系的主要热裂解气相产物的组成发生了变化,说明组分之间存在相互作用。压力对GAP/AP混合体系气相产物有明显的影响,表明混合体系组分GAP和AP之间的相互作用是通过AP分解气相产物进行的,混合体系不但存在气相之间的反应,也存在气相/凝聚相反应。而温度并没有影响AP对GAP的作用。用T-Jump/FTIR在线分析技术能够实现模拟燃烧条件下含能材料实时气体产物分析,为从微观反应的角度探索含能材料的快速高压热裂解及其组分之间的相互作用提供一条技术途径。The rapid pyrolysis of GAP/AP system under simulated combustion conditions was investigated by an on-line analysis,i.e.so called T-Jump/FTIR.The results show that the compositions of the main gaseous products for pyrolysis are changed,in comparison with the pyrolyses of single,which indicates that the interactions occur between the components of GAP/AP system.From an obvious effect of pressure on the main gaseous products for GAP/AP pyrolysis it is shown that the interactions between GAP and AP components arise from the gaseous products of AP and both the reactions in gas phase and in gas/condensed phase occur in the GAP/AP mixed system.The interactions between GAP and AP are not affected by test temperature.It is considered that the real time analysis of gaseous products of energetic material pyrolysis under simulated combustion conditions would be carried out by T-Jump/FTIR on-line analysis technique and from microcosmic reaction a technical approach used to explore the rapid pyrolysis of energetic materials and interactions between their components at high temperature and pressure would be developed by the on-line analysis technique from microcosmic reaction.

关 键 词：物理化学 在线分析 T-Jump FTIR联用技术 GAP AP混合体系 热裂解 

分 类 号：O657.3[理学—分析化学]