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作 者:Dehua XIONG Wei CHEN
出 处:《Frontiers of Optoelectronics》2012年第4期371-389,共19页光电子前沿(英文版)
摘 要:Tandem structured dye-sensitized solar cells (DSSCs) can take full advantage of sunlight, effectively broadening the absorption spectrum of the cell, resulting in a higher open circuit voltage or short circuit current than that of the conventional DSSC with single light absorber. The theoretical maximum efficiency is therefore suggested to be over the Schottky-Queisser limit of 33%. Accord- ingly, tandem design of DSSC is thought to be a promising way to break the performance bottleneck of DSSC. Besides, the tandem designs also broaden the application diversity of DSSC technology, which will accelerate its scale-up industrial application. In this paper, we have reviewed the recent progress on photo-electrochemical applications associated with kinds of tandem designs of DSSCs, in general, which are divided into three kinds: "n- type DSSC + n-type DSSC," "n-type DSSC + p-type DSSC" and "n-type DSSC +other solar conversion devices." The working principles, advantages and chal- lenges of these tandem structured DSSCs have been discussed. Some possible solutions for further studies have been also pointed out together.Tandem structured dye-sensitized solar cells (DSSCs) can take full advantage of sunlight, effectively broadening the absorption spectrum of the cell, resulting in a higher open circuit voltage or short circuit current than that of the conventional DSSC with single light absorber. The theoretical maximum efficiency is therefore suggested to be over the Schottky-Queisser limit of 33%. Accord- ingly, tandem design of DSSC is thought to be a promising way to break the performance bottleneck of DSSC. Besides, the tandem designs also broaden the application diversity of DSSC technology, which will accelerate its scale-up industrial application. In this paper, we have reviewed the recent progress on photo-electrochemical applications associated with kinds of tandem designs of DSSCs, in general, which are divided into three kinds: "n- type DSSC + n-type DSSC," "n-type DSSC + p-type DSSC" and "n-type DSSC +other solar conversion devices." The working principles, advantages and chal- lenges of these tandem structured DSSCs have been discussed. Some possible solutions for further studies have been also pointed out together.
关 键 词:dye-sensitized solar ceils (DSSCs) tandemstructure photo-electrochemical cell
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