一种以氮原子为中心的三脚架结构席夫碱的合成与配位性能研究  

The Synthesis and Coordination Property of a New Tripodal Schiff Base with N as Central Atom

作　　者：张敬[1] 

机构地区：[1]济宁学院化学与化工系,山东曲阜273155

出　　处：《济宁学院学报》2012年第6期19-21,共3页Journal of Jining University

摘　　要：以三乙醇胺、水杨醛、苯胺为初始原料,合成了一个新型的三脚架结构席夫碱,以这种席夫碱为配体与过渡金属氯化物或硝酸盐反应制备了多种过渡金属的配合物,通过元素分析、红外光谱、紫外光谱、核磁共振谱等化学物理手段进行了结构表征,确定了配体及配合物的组成,并对配体及配合物进行了杀菌活性研究.A kind of new tripodal schiff base was prepared by using triethanolamine, salicylaldehyde and aniline as materials. Then we prepared the complexes of the tripodal schiff base with transition metal chlorides or nitrates . The tripodal schiff base ligand and its complexes were characterized by elemental analyses, IR, UV, HNMR. The composition of the ligand and complexes are confirmed, Germicidal activation of the ligand and complexes are studied.

关 键 词：三脚架 西佛碱 配合物 合成 

分 类 号：O611.4[理学—无机化学]